Synergistic Impact of Sonophotocatalytic Degradation of Acephate Over Ag@CeO2 Nanocomposite Catalysts
Year: 2025
Type: article
Abstract: Noble metal decorated metal oxide composites have proved to have Surface plasmon resonance (SPR) as a notable approach for efficient light absorption. Herein present work, a new sonochemical method is proposed for in-situ synthesis of noble metal-based CeO2 composites for the sonophotocatalytic degradation of commercial Acephate solution. Pristine CeO2 and Ag@CeO2 with different Ag contents viz. 4, 6 and 8 wt. % were successfully synthesized by a facile in-situ sonochemical approach. The as-synthesized CeO2 and Ag@CeO2 nanocomposites were characterized by various physicochemical characterization techniques, including XRD, FTIR, UV-Vis spectroscopy, BET, and FESEM-EDS. Further, these CeO2 and Ag@CeO2 nanocomposites were employed for photocatalytic, sonocatalytic, and sonophotocatalytic degradation of commercial Acephate solution. Experimental results revealed that the photocatalytic and sonocatalytic processes follow a pseudo-first-order model, whereas the sonophotocatalytic process had a more substantial rate constant compared to the photocatalytic and sonocatalytic one. Further, the kinetics of the study were examined by the Langmuir-Hinshelwood model. Overall, the sonophotocatalytic degradation involving as-synthesized Ag@CeO2 with 6 wt. % Ag content has shown to be the most effective method for the effective degradation of a commercial acephate solution.
Language: English
Field: Energy
Domain: Physical Sciences
Open Access status: gold
Estimated APC paid: $575
OpenAlex ID: W4408101575