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(5,6-Dimethyl-1,10-phenanthroline)(2-{[2-(diphenylphosphanyl)benzylidene]amino}ethan-1-amine)platinum(II) dinitrate methanol disolvate

Year: 2025

Type: article

Abstract: The title compound, [Pt(C14H12N2)(C21H21N2P)](NO3)2·2CH3OH, is a platinum(II) complex, which crystallizes in a monoclinic (P21/c) space group. The complex exhibits a distorted square-planar geometry, which includes a monodentate 5,6-dimethyl-1,10-phenanthroline ligand and a tridentate 2-{[2-(diphenylphosphanyl)benzylidene]amino}ethan-1-amine ligand. The structure reveals both intra- and intermolecular π-stacking interactions between the phenanthroline and phosphine rings. Hydrogen bonding is observed between the complex ion, nitrate counter-ions and solvent molecules.

Source: Acta Crystallographica Section E Crystallographic Communications

DOI: 10.1107/s2056989025001847

Authors: Ashley Jurisinec, Yingjie Zhang, Janice R. Aldrich-Wright

Institutions: Western Sydney University, Australian Nuclear Science and Technology Organisation

Language: English

Topic: Crystal structures of chemical compounds

Subfield: Inorganic Chemistry

Field: Chemistry

Domain: Physical Sciences

Open Access status: gold

Estimated APC paid: $500

OpenAlex ID: W4408153640

FWCI:

Cites: 21

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Related to: 10