Work

Temperature-Dependent Morphology Modulation of MoO2 from 1D Nanoribbons to 2D Nanoflakes for Enhanced Two-Dimensional Electrode Applications

Year: 2025

Type: article

Abstract: The morphology modulation of target crystals is important for understanding their growth mechanisms and potential applications. Herein, we report a convenient method for modulating the morphology of MoO2 by controlling different growth temperatures. With an increase in growth temperature, the morphology of MoO2 changes from a nanoribbon to a nanoflake. Various characterization methods, including optical microscopy, atomic force microscopy, (vertical and tilted) scanning electron microscopy, Raman spectroscopy, high-resolution transmission electron microscopy, and selected area electron diffraction, were performed to unveil the morphology modulation and lattice structure of MoO2. Both MoO2 nanoribbons and nanoflakes display a standing-up growth mode on c-sapphire substrates, and their basal planes are MoO2(100). Further investigations into devices based on MoS2 with Au/Ti/MoO2 electrodes show the potential applications of MoO2 in two-dimensional electrodes. These findings are helpful for the synthesis of MoO2 with different morphologies and applications in the field of optoelectronic nanodevices.

Source: Nanomaterials

DOI: 10.3390/nano15050392