Ion selectivity and electrosorption of pseudocapacitive NiFe2O4 nanocrystals
Year: 2025
Type: article
Abstract: • Pseudocapacitive NFO nanocrystals were synthesized to evaluate their ion selectivity • The NFO electrodes demonstrated remarkable preference for SO₄²⁻ over Cl⁻ • NFO and rGO electrodes delivered comparable salt adsorption capacities • The excellent electrosorption of the NFO was attributed to crystalline intercalation Pseudocapacitive NiFe 2 O 4 (NFO) nanocrystals and reduced graphene oxide (rGO) nanosheets were synthesized, and their ion selectivity and electrosorption performance were evaluated. The NFO cathode-anode pair demonstrated a remarkable preference for SO 4 2− over Cl − , achieving a selectivity coefficient 76 within the first 30 minutes. This pronounced selectivity for anion SO 4 2− was primarily attributed to its higher divalent negative charge, which induced a stronger electrostatic attraction to the positively charged NFO electrode surface (+15.2 mV). Both materials delivered comparable salt adsorption capacities (SAC) of 231 mg g −1 for NFO and 243 mg g −1 for rGO in Al(NO 3 ) 3 .9H 2 O solution. The superior electrosorption performance of the NFO electrode was not attributed to its surface area, which was very low due to the non-porous material; instead, it was due to NFO's well-defined crystalline lattice spacing and available interstitial spaces enabled efficient ion intercalation and electrosorption. A key advantage of NFO was its exceptional divalent anion selectivity, where the electrode adsorbed 2.84 times more SO 4 2− ions than Cl − ions, demonstrating a high selectivity that usually cannot be achieved by electric double-layer (EDL)-based electrodes. These results highlight NFO electrodes as a promising alternative electrode material for compact and energy-efficient capacitive deionization (CDI) systems, particularly for applications demanding superior ion selective separation.
Source: Electrochimica Acta
Authors: Rahat Alam, Ahmed Alhajaj, Linda Zou
Language: English
Subfield: Biomedical Engineering
Field: Engineering
Domain: Physical Sciences
Open Access status: hybrid
Estimated APC paid: $3,790
OpenAlex ID: W4408217763