Work

AgNO3 catalysed oxidation of aromatic amines in the presence of hydrogen peroxide

Year: 2025

Type: article

Abstract: An operationally simple complementary oxidative dimerization of anilines to the corresponding azoxy derivatives by means of AgNO 3 catalysis in the presence of H 2 O 2 as the oxidant is described. Unusual activation of C C triple bonds in the presence of AgNO 3 -H 2 O 2 and amines is expected to facilitate advancements in the applications for silver catalysis in organic synthesis. • Oxidative dimerization of anilines. • Silver-catalyzed oxidation of primary amines with H 2 O 2 . • Synthesis of aromatic azoxy compounds.

Source: Tetrahedron Letters

DOI: 10.1016/j.tetlet.2025.155511

Authors: Vincenzo Marsicano, Antonio Arcadi, Marco Chiarini

Institutions: University of L'Aquila, University of Teramo

Language: English

Topic: Oxidative Organic Chemistry Reactions

Subfield: Organic Chemistry

Field: Chemistry

Domain: Physical Sciences

Open Access status: hybrid

Estimated APC paid: $3,610

OpenAlex ID: W4408427743

FWCI:

Cites: 36

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Related to: 10