Deriving the numerical value of LIB mathematical model parameters from experiments: Case of as-formed and aged NMC/LMO cathodes
Year: 2025
Type: article
Abstract: This study presents an experimental approach to the parameterization of lithium-ion battery cathodes for the Pseudo-Two-Dimensional (P2D) model, focusing on blended NMC532/LMO, commonly used in automotive batteries. Specifically, we are proposing an Experimental Battery Parameterization (EBP) protocol to determine key material parameters through direct measurement rather than relying on literature values. The research examines as-formed and aged cathodes, revealing significant changes in electrochemical behaviour, structural integrity, and material composition after ageing. Ageing effects, such as particle fracture, increased lithium content, and changes in porosity and conductivity, were observed. While as-formed cathodes showed higher theoretical capacities, aged ones exhibited lower activation energies for lithium diffusion, indicating enhanced ion mobility, accompanied by structural degradation. Our study emphasizes that experimental parameterization, especially in the case of aged batteries, is essential to have a precise grasp over the scope and limitations of the P2D model and identify areas for model improvement. • Developed a protocol for accurate battery model parameter estimation. • Analysed NMC523-LMO cathodes from as-formed and aged commercial batteries. • Captured material-specific degradation impacts on performance and structure. • Findings P2D model limitations and areas for targeted extensions. • Integrated experimental data to enhance real-world LIB simulation accuracy.
Source: Journal of Energy Storage
Institution: Politecnico di Milano
Language: English
Subfield: Automotive Engineering
Field: Engineering
Domain: Physical Sciences
Open Access status: hybrid
Estimated APC paid: $3,560
OpenAlex ID: W4408457563