Work

Unveiling Crystalline Order from Glassy Behavior of Charged Rods at Very Low Salt Concentrations

Year: 2025

Type: article

Abstract: Charged colloids can form ordered structures like Wigner crystals or glasses at very low concentrations due to long-range electrostatic repulsions. Here, we combine small-angle x-ray scattering (SAXS) and optical experiments with simulations to investigate the phase behavior of charged rodlike colloids across a wide range of salt concentrations and packing fractions. At ultralow ionic strength and packing fractions, we reveal both experimentally and numerically a direct transition from a nematic to a crystalline smectic-B phase, previously identified as a glass state. This transition, bypassing the smectic-A intermediate phase, results from minimizing Coulomb repulsion and maximizing entropic gains due to fluctuations in the crystalline structure. This demonstrates how long-range electrostatic repulsion significantly alters the phase behavior of rod-shaped particles and highlights its key role in driving the self-organization of anisotropic particles.

Source: Physical Review Letters

DOI: 10.1103/physrevlett.134.118101

Authors: Hanna Anop, Laura Dal Compare, Frédéric Nallet, Achille Giacometti, Eric Grelet

Institutions: Centre National de la Recherche Scientifique, Université de Bordeaux, Centre de recherche Paul Pascal, Ca' Foscari University of Venice, European Centre for Living Technology

Language: English

Topic: Electrostatics and Colloid Interactions

Subfield: Physical and Theoretical Chemistry

Field: Chemistry

Domain: Physical Sciences

Open Access status: green