Work

Mixed ionic conductor brings extra gain in oxygen-evolving activity of NiFe hydroxide electrocatalyst at practical working temperature

Year: 2025

Type: article

Abstract: Industrial water electrolysis typically occurs at temperatures higher than ambient. The anodic oxygen evolution reaction (OER) in water electrolysis is inherently temperature-dependent, with enhancements in thermodynamics and kinetics at higher temperatures. However, it is often overlooked that material properties at elevated temperatures can differ significantly from those at room temperature. In this study, NiFe-based layered double hydroxide (LDH)/CeO2 is utilized as anodic electrocatalyst for both ambient- and elevated-temperature water/seawater electrolysis. The optimal catalyst displays favorable oxygen conductivity and thus enhanced OER activity. The partial coverage of LDH with CeO2 effectively mitigates direct chlorine adsorption. Additionally, its high proton conductivity prevents proton accumulation within LDH interlayers and ensures stability. Notably, the enhanced mixed ionic conductivities at elevated temperature contribute to significant improvements in OER performance. This study underscores the effectiveness of employing mixed ionic conductors for OER and highlights the importance of characterizing OER process under elevated temperature for practical applications.

Source: Applied Catalysis B: Environmental

DOI: 10.1016/j.apcatb.2025.125271

Authors: Lu Li, Liqi Bai, Sixuan She, Gao Chen, Haitao Huang

Institution: Hong Kong Polytechnic University

Language: English

Topic: Electrocatalysts for Energy Conversion

Subfield: Renewable Energy, Sustainability and the Environment

Field: Energy

Domain: Physical Sciences

SDGs: Affordable and clean energy, Clean water and sanitation

Open Access status: hybrid

Estimated APC paid: $5,950