Atomic Layer Thickness Modulated the Catalytic Activity of Platinum for Oxygen Reduction and Hydrogen Oxidation Reaction
Year: 2025
Type: article
Abstract: Reducing platinum (Pt) usage and enhancing its catalytic performance in the hydrogen oxidation reaction (HOR) and the oxygen reduction reaction (ORR) are vital for advancing fuel cell technology. This study presents the design and investigation of monolayer and few‐layer Pt structures with high platinum utilization, developed through theoretical calculations. By minimizing the metal thickness from 1 to 3 atomic layers, an atomic utilization rate ranging from 66.66% to 100% is achieved, in contrast to conventional multilayer Pt structures. This reduction resulted in a unique surface coordination environment. These thinner structures exhibited nonlinear fluctuations in key electronic characteristics—such as the d‐band center, surface charge, and work function—as the atomic layer thickness decreased. These variations significantly impacted species adsorption and the Pt‐H2O interfacial structure, which in turn affected the catalytic activity. Notably, 1‐layer Pt exhibited the best performance for HOR, while 3‐layer Pt showed high activity for both HOR and ORR. The findings establish a clear relationship between atomic layer thickness, surface characteristics, adsorption behavior, electric double‐layer structure, and catalytic performance in Pt systems. This research contributes to a deeper understanding of precision atomic‐structured electrocatalyst design and paves the way for the development of highly effective, low‐loading Pt‐based catalytic materials.
Source: Small Methods
Authors: Shengyao Lv, Jin Liu, Zhuoyang Xie, Li Li, Zidong Wei
Institution: Chongqing University
Language: English
Field: Energy
Domain: Physical Sciences
Open Access status: bronze
OpenAlex ID: W4408633871