Investigation of Structural, Optical, and Frequency-Dependent Dielectric Properties of Barium Zirconate (BaZrO3) Ceramic Prepared via Wet Chemical Auto-Combustion Technique
Year: 2025
Type: conference-paper
Abstract: The wet chemical auto-combustion technique was used to synthesize barium zirconate ceramic (BaZrO3). Many strategies were applied to regulate the functional properties of the perovskite-structured sample which was calcinated at 800 °C for 9 h. A Fourier-transform IR spectrometer, an X-ray diffractometer, a scanning electron microscope (SEM)-EDAX, an LCR meter, and a UV–visible spectrometer were employed to study the structural, morphological, optical, and electrical properties of the prepared barium zirconate sample. Using data derived from XRD, the perovskite phase was confirmed, and the average value of the crystallite size was found to be 17.68 nm. The lattice constant, crystallinity, unit cell volume, tolerance factor, and X-ray density were also calculated. SEM-EDAX confirmed the elemental composition of the product and verified that it contained only the major constituents (Ba, Zr, and O). The vibrational modes of the prepared sample were investigated using FTIR in wavelengths ranging from 400 to 4000 cm−1. Energy bandgap was observed using Tauc’s plot, where a graph was prepared for photon energy (hυ) and (αhυ)2. The powder sample was blended with PVA and made into pellets of 13 mm diameter using a pelletizer to explore dielectric parameters like the dielectric constant, while the loss factor was recorded at a frequency ranging from 100 Hz to 4 MHz at room temperature. With its high dielectric constant and low dielectric loss factor, barium zirconate ceramic stands as an excellent material for several microwave applications.
Authors: Anitha Gnanasekar, Pavithra Gurusamy, Geetha Deivasigamani
Institution: Anna University, Chennai
Language: English
Subfield: Materials Chemistry
Field: Materials Science
Domain: Physical Sciences
Open Access status: gold
OpenAlex ID: W4408674672