Construction of Hierarchical 2D-3D@3D Zn3In2S6@CdS Photocatalyst for Boosting Degradation of an Azo Dye
Year: 2025
Type: article
Abstract: Herein, flower-like Zn3In2S6 (ZIS3) crystallites were grown onto acorn leaf-like CdS assemblies via a two-step hydrothermal approach. Under visible light irradiation, the Zn3In2S6-enriched heterostructures demonstrated an enhanced azo-dye degradation rate, with the majority of the organic analyte (Orange G) being degraded within 60 min. In contrast, the CdS-enriched hybrids showed poor photocatalytic performance. The optimized hybrid containing a nominal CdS content of 4 wt% was characterized by various physicochemical techniques, such as XRD, SEM, XPS and Raman. XPS analysis showed that the electron density around the Zn and In sites in Zn3In2S6 was slightly increased, implying a certain charge migration pattern. Complementary information from scavenging experiments suggested that hydroxy radicals were not the exclusive transient responsible for oxidative degradation of the organic azo-dye. This research provides new information about the development of metal chalcogenide-based heterostructures for efficient photocatalytic organic pollutant degradation.
Source: Molecules
Language: English
Field: Energy
Domain: Physical Sciences
Open Access status: gold
Estimated APC paid: $3,258
OpenAlex ID: W4408768952