Tubular Nanostructures from Large‐Pore 2D Covalent Organic Frameworks
Year: 2025
Type: article
Abstract: The synthesis of a wavy mesoporous 2D covalent organic framework (COF) with a 6-nm hexagonal pore lattice (Joa-COF-1) is reported. This has been achieved by the synthesis of a terpyrenyl linker of approximately 2.7 nm in length and its subsequent condensation with a 3-connected non-planar cata-hexabenzocoronene. Joa-COF-1 exists as non-covalent tubular domains composed of π-stacked 4 to 5 pores in 2D COF sections that can be separated by mild sonication, resulting in a family of tubular COF nanostructures that combine a 1D morphology with accessible mesopores.
Authors: Joaquín Almarza, Ian Cardillo‐Zallo, Karol Strutyński, Marta Martínez‐Abadía, Natalia M. Padial, Carlos Martí‐Gastaldo, Manuel Melle‐Franco, Andrei N. Khlobystov, Aurelio Mateo‐Alonso
Language: English
Subfield: Materials Chemistry
Field: Materials Science
Domain: Physical Sciences
Open Access status: hybrid
Estimated APC paid: $5,510
OpenAlex ID: W4408780362