Work

Non-adiabatic photodissociation dynamics of vinyl iodide from nσ* and nπ* transitions

Year: 2025

Type: article

Abstract: π* transition. The subsequent dissociation dynamics from that state features an ultrafast electronic predissociation with sub-200 femtosecond reaction time. State-switching at a first CI with a low-lying electronic state governing the mechanism involves states of completely different character, occurring in less than 20 fs. This remarkably fast process takes place through an initial stretch of the CC bond, followed by a C-I elongation with subsequent vibrational activity in the CC stretch mode.

Source: Physical Chemistry Chemical Physics

DOI: 10.1039/d5cp00236b

Authors: Marta L. Murillo-Sánchez, Sonia Marggi Poullain, Paulo Limão-Vieira, Alexandre Zanchet, Nelson de Oliveira, Jesús González-Vázquez, Luis Bañares

Institutions: Universidad Complutense de Madrid, Consejo Superior de Investigaciones Científicas, Universidade Nova de Lisboa, Instituto de Física Fundamental, Synchrotron SOLEIL, Universidad Autónoma de Madrid, IMDEA Nanoscience

Language: English

Topic: Laser-Matter Interactions and Applications

Subfield: Atomic and Molecular Physics, and Optics

Field: Physics and Astronomy

Domain: Physical Sciences

Open Access status: hybrid

Funders: Comunidad de Madrid, Ministerio de Ciencia, Innovación y Universidades, Universidad Complutense de Madrid, Ministerio de Ciencia e Innovación, Association Franck, Un Rayon de Soleil, Dirección General de Universidades e Investigación

Awards: G1156664317, G1280488104, G4043276, G4402643818, G5209985526, G5664692205, G6976476504, G900983691

OpenAlex ID: W4408843540

FWCI:

Cites: 51

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Related to: 10