Work

Ion diffusivity and alkyl chain length-dependent triboelectric behavior of PVDF-HFP+IL composites

Year: 2025

Type: article

Abstract: • Ionic liquids were incorporated into PVDF-HFP to create an electric double layer in TENG, significantly improving output performance. • Cations with short alkyl chains demonstrated tribo-positive characteristics, whereas those with long alkyl chains exhibited tribo-negative behavior. • The disparity in ion diffusivity between cations and anions plays a key role in regulating the triboelectric properties of the ionic liquid polymer composite. As the global demand for renewable and clean energy solutions grows, triboelectric nanogenerators (TENGs) have emerged as a promising technology for harvesting mechanical energy. In this context, our study focuses on incorporating ionic liquids (ILs) into poly(vinylidene fluoride-co-hexafluoropropylene) (PVDF-HFP) to explore how the alkyl chain length of ILs influences triboelectric polarity. Imidazolium-based ILs containing bis(trifluoromethylsulfonyl)imide (TFSI⁻) anions were used, with cations such as 1-ethyl-3-methylimidazolium (EMIM⁺) and 1-butyl-3-methylimidazolium (BMIM⁺) exhibiting tribo-positive characteristics, while those with longer alkyl chains, including 1-methyl-3-n-octylimidazolium (OMIM⁺) and 1-dodecyl-3-methylimidazolium (DoMIM⁺), displayed tribo-negative behavior. These trends were correlated with self-diffusion coefficient measurements of the ILs. The control of triboelectric behavior and the formation of an electric double layer (EDL) through IL incorporation significantly enhanced the surface charge density, thereby improving the output performance of TENGs. This work provides a novel strategy for enhancing TENG efficiency and offers material selection guidelines for sustainable energy applications. Incorporating ionic liquids (ILs) into PVDF-HFP influences triboelectric polarity in TENGs. Imidazolium-based ILs with shorter alkyl chains exhibit tribo-positive behavior, while longer chains show tribo-negative characteristics. Self-diffusion coefficients correlate with these trends, enhancing surface charge density and improving TENG output performance through electric double layer formation.

Source: Nano Trends

DOI: 10.1016/j.nwnano.2025.100104