Work

Photochemistry of Methyl Formate Radical Cations in Frozen Cfcl3 Matrices

Year: 2025

Type: article

Abstract: A novel mechanism has been discovered for the phototransformations of methyl formate radical cations (RCs) wherein an RC that is furnished upon thermally induced 1,2-transfer of an hydrogen atom in the methyl group to the bridging oxygen atom undergoes photoinduced H+ transfer to the matrix.

Source: Lomonosov chemistry journal

DOI: 10.55959/msu0579-9384-2-2025-66-2-100-106

Authors: Mikhail Ya. Melnikov, Oleg I. Gromov, Vladimir I. Pergushov, Daria A. Pomogailo, Ivan D. Sorokin

Institutions: Lomonosov Moscow State University, D. Mendeleyev University of Chemical Technology of Russia

Language: English

Topic: Chemical Reactions and Mechanisms

Subfield: Physical and Theoretical Chemistry

Field: Chemistry

Domain: Physical Sciences

Open Access status: bronze

OpenAlex ID: W4408891290

FWCI:

Cites: 8

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Related to: 10