Work

SrZnGeSe 4 : a promising infrared nonlinear optical material with strong second harmonic generation and high laser-induced damage threshold

Year: 2025

Type: article

Abstract: Developing new infrared (IR) nonlinear optical (NLO) materials with strong NLO response and wide band gap is highly desired in the NLO fields but challenging due to the contradiction between the two critical parameters. In this work, by optimizing the advantageous structural motifs, a new selenide IR NLO candidate SrZnGeSe 4 was rationally designed, fabricated, and validated in the experiment. Structurally, SrZnGeSe 4 is composed of [ZnSe 4 ], [GeSe 4 ], and [SrSe 8 ] units, resulting in a tunnel-like three-dimensional structure. The synergistic effect of polyhedral units in SrZnGeSe 4 gives rise to balanced optical properties, including a wide band gap (2.5 eV) in selenides, a strong NLO response (1.8 × AgGaS 2 ), and a high laser-induced damage threshold (3.3 × AgGaS 2 ). The density functional theory calculations uncover that the wide optical band gap and large NLO effect in SrZnGeSe 4 are primarily governed by the advantageous [ZnSe 4 ] and [GeSe 4 ] NLO-active units. The experimental and theoretical results indicate that SrZnGeSe 4 is a promising IR NLO candidate and give some new insights into the design of new IR NLO materials with high performance.

Source: Optics Express

DOI: 10.1364/oe.555811

Authors: Hongshan Wang, Ran An, Yinxia Du, Shilie Pan, Junjie Li

Institution: Xinjiang Technical Institute of Physics & Chemistry

Language: English

Topic: Crystal Structures and Properties

Subfield: Electronic, Optical and Magnetic Materials

Field: Materials Science

Domain: Physical Sciences

Open Access status: gold

Estimated APC paid: $2,270

Funder: National Natural Science Foundation of China