Work

Morphology transition engineering on MgO for enhanced dye adsorption without using surfactants as sacrifice templates

Year: 2025

Type: article

Abstract: • A simple strategy can optimize the simple morphology of MgO into an embroidered ball-shaped morphology without using surfactants as sacrifice templates, which increase Brunauer-Emmett-Teller surface area of MgO by 2–3.51 times. • Molecular dynamics simulations confirm the different crystalline facets of MgO have different affinities for Cong red molecules. • NM-24 shows an ultrahigh adsorption capacity of 7236.62 mg g −1 to Cong red, the highest ever recorded, and excellent recyclability for at least 5 cycles. • The role of low-coordinated oxygen anions for enhanced adsorption performance of NM-24 was illustrated in detail for the first time. Hierarchical porous MgO is a promising adsorbent for dye removal because of its large Brunauer–Emmett–Teller specific surface area ( S BET ) and abundant low-coordinated oxygen anions (LCO) sites. As hierarchical porous MgO particles with large S BET values are typically prepared by complicated procedures under harsh conditions, such as high temperatures and high pressures, their large-scale production is impractical. Consequently, the preparation of hierarchical porous MgO with a large S BET value under mild conditions is highly desirable. In this study, a morphology transition engineering strategy is introduced to change the morphology of simple MgO microspheres to an embroidered ball-shaped with a larger S BET value via hydrolysis and calcination without using surfactants as sacrificial templates. During hydrolysis, numerous Mg(OH) 2 sheets form and attach to the MgO surface, thus increasing the S BET value of the newly obtained MgO that forms by calcination (denoted as NM- x , where x is the hydrolysis time in hours). The sizes of the crystalline sheets were tuned by controlling the hydrolysis time. NM-12 exhibited the highest density of small-sized sheets on its surface and the largest S BET value of 180.17 m 2 g −1 , which was 3.51 times that of the MgO precursor (51.89 m 2 g −1 ). However, NM-24 (134.07 m 2 g −1 ) had a higher adsorption efficiency for Congo red (CR) than NM-12, despite having a smaller S BET value, which indicates that other factors are involved. NM-24 exhibited a lower probability of exposed (200) and (220) facets which were verified to repulse CR molecules by molecular dynamics simulations, and a greater number of LCO sites, which contributed to adsorption. Thus, this study introduces a facile method for preparing hierarchical porous MgO and examines the effects of LCO sites and exposed facet probabilities on its adsorption properties.

Source: Journal of Magnesium and Alloys

DOI: 10.1016/j.jma.2025.02.019