Constructing Multifunctional Composite Paper Coated with Polypyrrole@Lignocellulosic Slurry with Humidity Sensing, Conductivity, Antibacterial, and Photothermal Properties
Year: 2025
Type: article
Abstract: A multifunctional paper-based composite of paper coated with a polypyrrole@lignocellulosic slurry (PPy@LS) and carboxymethyl cellulose (CMC) was developed. PPy@LS was prepared via the polymerization of pyrrole onto a lignocellulosic slurry derived from hemp stalks prepared using deep eutectic solvents. The PPy@LS slurry was mixed with the required amount of CMC and vacuum-filtered onto filter paper to fabricate the composite (PPy@LS/CMC). The resulting composite paper exhibited excellent multifunctional properties, including electrical conductivity, photothermal conversion, and antibacterial properties. These properties are stable against external environments, such as water and abrasion, due to the addition of CMC. The electrical conductivity of PPy@LS/CMC varied in the dry (1.6 × 10−4 S/cm) and wet (4.8 × 10−6 S/cm) states, suggesting its potential application in humidity sensing. Notably, the PPy@LS/CMC paper achieved significant photothermal activity under light irradiation, as demonstrated by the measured surface temperature exceeding 80 °C in 10 min. Moreover, the composite paper exhibited > 99.9% antibacterial activity against Escherichia coli (Gram-negative) and Staphylococcus aureus (Gram-positive). The combination of the inherent characteristics of filter paper along with the photothermal property of PPy enable the PPy@LS/CMC composite appropriate for solar interfacial evaporation application. These multifunctional composite papers with innovative combinations of properties have great potential for applications in smart packaging, humidity sensing, biomedicine, and solar-driven water purifications.
Source: Polymers
Authors: Qingrun Ni, Yating Wang, Shoujuan Wang, Magdi E. Gibril, Fangong Kong
Institutions: Qilu University of Technology, Shandong Academy of Sciences
Language: English
Subfield: Biomaterials
Field: Materials Science
Domain: Physical Sciences
Open Access status: gold
Estimated APC paid: $3,258
OpenAlex ID: W4408938976