Work

Sustainable Recycling of TiO2 Nanoparticles with High Photocatalytic Performance from Spent Selective Catalytic Reduction Catalysts

Year: 2025

Type: article

Abstract: In this work, a sustainable approach to reclaiming high-value anatase/rutile TiO2 nanoparticles from deactivated or used selective catalytic reduction (SCR) catalysts is demonstrated using a composite flux (NaOH/Na2CO3) through an efficient sintering and subsequent leaching methodology. This method directly addresses the urgent need for circular economy strategies in industrial waste management. Sintering experiments revealed that while NaOH enhanced the separation efficiency of V2O5 and SiO2, it led to agglomerated products, hindering TiO2 recovery. In contrast, Na2CO3 enabled the production of powdery sintered residues, facilitating the complete separation of anatase/rutile TiO2 nanoparticles, as confirmed by XRD. By optimizing the sintering-leaching conditions, this method achieves near-total recovery of TiO2 with retained photocatalytic performance, ensuring its suitability for reuse in applications such as air/water purification or renewable energy systems. This study advances sustainability by repurposing industrial waste into high-performance materials, reducing the energy and resource demands associated with conventional TiO2 synthesis, and preventing hazardous material leakage into ecosystems. The scalable, low-complexity process aligns with global sustainability goals, including responsible consumption (SDG 12), climate action (SDG 13), and industrial innovation (SDG 9), offering a blueprint for transforming waste streams into valuable resources for a greener economy.

Source: Sustainability

DOI: 10.3390/su17073003

Authors: Zhaoming Lu, Xiaojing Xi, Yanling Yang, Wenjie Tian, Bin Xu, Hua-Jun Chen

Institutions: Luoyang Institute of Science and Technology, Shaanxi University of Science and Technology

Language: English

Topic: TiO2 Photocatalysis and Solar Cells

Subfield: Renewable Energy, Sustainability and the Environment

Field: Energy

Domain: Physical Sciences

SDGs: Responsible consumption and production, Clean water and sanitation, Industry, innovation and infrastructure

Open Access status: gold

Estimated APC paid: $2,896