Work

Removal of heavy metal ions in wastewater and reuse as a hydrogenolysis catalyst: Multistage application of lignin-based adsorbent

Year: 2025

Type: article

Abstract: Heavy metals in industrial wastewater represent a significant threat to the ecosystem and need to be efficiently removed before discharge. However, the effective utilization of heavy metals using affordable and efficient processes still poses a sustainability challenge. Here, we report a sustainable regeneration of spent heavy metal ions from lignin-based adsorbents toward efficient reductive catalytic degradation of lignin into monophenols. A reverse suspension strategy was first used to cross-link small molecules of industrial lignin waste into long-chain macromolecules using epichlorohydrin as a crosslinking agent. The long-chain macromolecules displayed a high affinity of Cu 2 + and Pb 2+ with maximum adsorption capacity of 393.9 mg/g and 349.2 mg/g, respectively. The adsorption isotherms and kinetics models revealed that Cu 2+ and Pb 2+ adsorption followed monolayer chemisorption. Notably, the regenerated carbon-loaded copper oxide (CuO/C) nanomaterial served as an effective catalyst for lignin deconstruction with a yield of monomeric phenols up to 25.9 wt%, which for the first time realized the multistage application of lignin-based adsorbents for the removal of heavy metal ions and their reuse as hydrogenolysis catalysts. This work paves a new way for the fabrication of bio-derived heterogeneous catalyst in wastewater treatment. • A novel strategy for multistage application of lignin-based adsorbents is proposed. • Lignin was cross-linked into long-chain macromolecules as efficient adsorbents. • Highly efficient and rapid removal of heavy metals from wastewater were achieved. • Adsorbents with Cu 2+ were fabricated into CuO/C catalysts for lignin hydrogenolysis.

Source: Industrial Crops and Products

DOI: 10.1016/j.indcrop.2025.120919