Year: 2025
Type: article
Abstract: In this work, defect‐rich UiO‐66‐NH 2 metal–organic framework (MOF) anchoring on flower‐like NiCo layered double hydroxides (LDH), was developed for enhanced photocatalytic performance. Various analytical methods including positron annihilation lifetime spectroscopy (PALS) revealed that deuteration reduced defect‐related free volume and modified positron trapping, indicating structural densification and improved charge carrier separation. Thermogravimetric analysis (TGA) confirmed the presence of structural defects, affecting thermal stability and facilitating enhanced catalytic activity. This was further supported by the X‐ray photoelectron spectroscopy (XPS) which identified dominated Zr 3+ states in Defect UiO‐66‐NH2 (UiO‐66‐NH 2 ‐D), signifying electronic alterations that contribute to improved photocatalytic performance. Spectroscopic & electrochemical analysis demonstrated an extended charge carrier lifetime, and minimum charge transfer resistance indicating suppressed recombination rates in the defect‐engineered system compared to defect‐free MOF. Benefiting by the synergistic interactions between UiO‐66‐NH 2 ‐D and NiCo‐LDH, the UiO‐66‐NH 2 ‐D/NiCo‐LDH heterostructure composite achieves H₂ production rate of 7.6 mmol g −1 h −1 which is 2.18 and 3.5 times higher than UiO‐66‐NH 2 ‐D and pristine UiO‐66‐NH 2 , respectively, via seawater splitting. This study paves the way for developing defect‐engineered MOF‐based composites for renewable energy applications, particularly in utilizing seawater directly for hydrogen production.
Source: ChemCatChem
Authors: Aparna Jamma, Tutika Aishwarya Lakshmi, Mohsen Ahmadipour, Yendrapati Taraka Prabhu, Ujjwal Pal
Language: English
Field: Energy
Domain: Physical Sciences
Open Access status: bronze
Awards: G257882512, G8043649853
OpenAlex ID: W4409068730