Work

Controlled Vapor-Phase Synthesis of VSe2 via Selenium-Driven Gradual Transformation of Single-Crystalline V2O5 Nanosheets

Year: 2025

Type: article

Abstract: We report a gas-phase precursor modulation strategy for the controlled synthesis of 1T-phase vanadium diselenide (VSe2) from vanadium pentoxide (V2O5) nanosheets by systematically adjusting the vapor pressure of selenium. By controlling the selenium vapor pressure, selenium-free vapor transport of vanadium dioxide led to the spontaneous oxidation and formation of tens-of-micrometer-sized rectangular V2O5 crystals, while moderate selenium introduction produced intermediate oxygen-rich phases with trapezoidal crystal facets, and a highly selenium-rich environment yielded trigonal VSe2 crystals. Raman scattering measurements confirmed the stepwise transformation from V2O5 to VSe2, and atomic force microscopy revealed well-defined layered morphologies and distinct conformation within an atomically thin regime. Additionally, high-resolution transmission electron microscopy validated the orthorhombic and trigonal crystal structures of V2O5 and VSe2, respectively. This work demonstrates the versatility of fine-tuned vapor-phase growth conditions in vanadium-based layered compounds, providing useful platforms to optimize structural composition with atomic precision.

Source: Nanomaterials

DOI: 10.3390/nano15070548

Author: Gangtae Jin

Institution: Gachon University

Language: English

Topic: 2D Materials and Applications

Subfield: Materials Chemistry

Field: Materials Science

Domain: Physical Sciences

Open Access status: gold

Estimated APC paid: $2,896

Funders: National Research Foundation, Gachon University, National Research Foundation of Korea, Ministry of Science and ICT, South Korea