Work

Growth of Hexagonal Bn Crystals by Traveling-Solvent Floating Zone

Year: 2025

Type: article

Abstract: Large, high-purity single-crystals of hexagonal BN (h-BN) are essential for exploiting its many desirable and interesting properties. Here, we demonstrate via X-ray tomography, X-ray diffraction and scanning electron microscopy that h-BN crystals can be grown by traveling-solvent floating-zone (TSFZ). The diameters of grown boules range from 3 – 5 mm with lengths from 2 – 7 mm. Tomography indicates variable grain sizes within the boules, with the largest having areas of ≈ 1 mm × 2 mm and thickness ≈ 0.5 mm. Although the boules contain macroscale flux inclusions, the h-BN lattice itself is of high quality for samples grown under optimized conditions. The currently optimized growth procedure employs an Fe flux, moderate N2 pressure (PN2 ≈ 6 bar), and a growth rate of 0.1 mm/h. Raman spectroscopy for an optimized sample gives an average linewidth of 7.7(2) cm−1 for the E2g intralayer mode at 1365.46(4) cm−1 and 1.0(1) cm−1 for the E2g interlayer shear mode at 51.78(9) cm−1. The corresponding photoluminescence (PL) spectrum shows sharp phonon-assisted free exciton peaks and minimal signal in the energy range corresponding to carbon-related defects (E = 3.9 – 4.1 eV). Our work demonstrates the viability of growing h-BN by the TSFZ technique, thereby opening a new route towards larger, high-quality crystals and advancing the state of h-BN related research.

Source: Journal of Crystal Growth

DOI: 10.1016/j.jcrysgro.2025.128164