Work

Assessment of a new benzylidene-based corrosion inhibitor for X60 carbon steel in 1 M HCl medium: Experimental and computational studies

Year: 2025

Type: article

Abstract: The performance of the studied compound in this work namely, N-(5-nitro-2-hydroxybenzylidene) pyridine-2-amine (NH2PA) as an inhibitor for X60 steel corrosion in 1 M HCl was appraised via weight loss and electrochemical methods. The results revealed that NH2PA possessed excellent corrosion inhibition capability which increased with rise in its concentration. An inhibition efficiency of 97.3 % was attained at a low concentration (1.0 mM NH2PA). In addition, the elevation of solution temperature indicated a decline in the inhibition efficiency. Results from electrochemical test showed that the inhibitive behavior NH2PA was mixed type. The adsorption of NH2PA inhibitor system onto the X60 steel surface followed the Langmuir adsorption isotherm, showing a combined physical and chemical adsorption on the X60 steel surface. The surface morphology and adsorption of the inhibitor on the steel surface were confirmed using SEM. Theoretical computations were studied utilizing density functional theory (DFT) to aid in better evaluation of the inhibition mechanism and performance of NH2PA.

Source: Results in Surfaces and Interfaces

DOI: 10.1016/j.rsurfi.2025.100510

Authors: Nkem B. Iroha, Cordelia U. Dueke-Eze, Valentine Chikaodili Anadebe, Ngozi J. Maduelosi, Renjith Thomas, Eno E. Ebenso

Institutions: Federal University Otuoke, University of Lagos, Alex Ekwueme Federal University, Ndufu-Alike, Rivers State University, University of South Africa

Language: English

Topic: Corrosion Behavior and Inhibition

Subfield: Materials Chemistry

Field: Materials Science

Domain: Physical Sciences

Open Access status: gold

Estimated APC paid: $1,190

OpenAlex ID: W4409204253

FWCI: 1.039

Cites: 53

Cited by: 5

Related to: 10