Work

The Oxidation of Cyclic Ketones by H2O2 Catalyzed by Cu(II) and Fe(III) Coordination Polymers

Year: 2025

Type: article

Abstract: It has been shown that the oxidation of ketones – analogs of cyclohexanone – by hydrogen peroxide in the presence of Cu3(btc)2 (btc3- = 1,3,5-benzenetricarboxylate) occurred mainly by the radical mechanism, rather than by the Baeyer-Villiger reaction mechanism, and led to a mixture of products formed due to the ring cleavage and reduction of the hydrocarbon chain length. Unlike aliphatic ketones, α-tetralone hardly underwent conversion in the reaction with H2O2 in the presence of HKUST-1, and the oxidation of the same ketone in the presence of Fe2(OH)3(btc) led to the formation of a number of products; among them, 1,4-naphthoquinone was dominant.

Source: Journal of organic and pharmaceutical chemistry

DOI: 10.24959/ophcj.24.315358

Authors: Emir N. Abdullayev, Andrii M. Mishura, Ievgenii A. Iermolenko, Anton S. Lytvynenko, Maksim O. Kolosov, Olena G. Shvets, Kostyantyn S. Gavrilenko, Sergiy V. Kolotilov

Institutions: National Academy of Sciences of Ukraine, L.V. Pisarzhevskii Institute of Physical Chemistry, Institute of Organic Chemistry, V. N. Karazin Kharkiv National University, Taras Shevchenko National University of Kyiv

Language: English

Topic: Metal-Organic Frameworks: Synthesis and Applications

Subfield: Inorganic Chemistry

Field: Chemistry

Domain: Physical Sciences

Open Access status: diamond

OpenAlex ID: W4409216160

FWCI:

Cites: 43

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Related to: 10