Work

Tailored engineering of primary catalytic sites and secondary coordination spheres in metalloenzyme-mimetic MOF catalysts for boosting efficient CO 2 conversion

Year: 2025

Type: article

Abstract: A series of MOF catalysts UiO-67-(BPY-Cu)-F x were constructed, which exhibited remarkable metalloenzyme-mimetic behavior in the carboxylic cyclization between propargylamines and CO 2 , resulting in the highest TOF under similar conditions.

Source: Chemical Science

DOI: 10.1039/d5sc01004g

Authors: Jiawei Li, Fan Yang, Benling Yu, Zhongke Dai, Shiyuan Wei, Ying Wu, Liuqing He, Fa Zhou, Jianhan Huang, You-Nian Liu

Institutions: Central South University, Guangdong University of Technology, South China University of Technology, Second Xiangya Hospital of Central South University

Language: English

Topic: Carbon dioxide utilization in catalysis

Subfield: Process Chemistry and Technology

Field: Chemical Engineering

Domain: Physical Sciences

Open Access status: diamond

Funders: National Natural Science Foundation of China, Central South University, Guangzhou Municipal Science and Technology Project, Fundamental Research Funds for the Central Universities, Fundamental Research Funds for Central Universities of the Central South University, Basic and Applied Basic Research Foundation of Guangdong Province

Awards: G1544181504, G5822856064, G6544447978, G6601473805, G874423508

OpenAlex ID: W4409241059

FWCI: 0.559

Cites: 44

Cited by: 2

Related to: 10