Work

External electric fields drive the formation of P → C dative bonds

Year: 2025

Type: article

Abstract: valence bond (VB) theory calculations of the EF-driven dative bonds, aligning with the crucial role of the charge transfer interaction. This pronounced covalency emerges as a key feature of EF-driven interactions, setting them apart from traditional dative bonds studied in parallel throughout this work.

Source: Chemical Science

DOI: 10.1039/d5sc01701g

Authors: Tingting Ma, Xubin Wang, Xinru Peng, Jiayao Li, Shiwei Yin, Yirong Mo, Changwei Wang

Institutions: Shaanxi Normal University, University of North Carolina at Greensboro

Language: English

Topic: Advanced Chemical Physics Studies

Subfield: Atomic and Molecular Physics, and Optics

Field: Physics and Astronomy

Domain: Physical Sciences

Open Access status: diamond

Funders: National Science Foundation, Joint School of Nanoscience and Nanoengineering, National Natural Science Foundation of China, Division of Electrical, Communications and Cyber Systems

Awards: NNCI: Southeastern Nanotechnology Infrastructure Corridor (SENIC), G3754320130, G7061960672

OpenAlex ID: W4409266385

FWCI: 1.482

Cites: 138

Cited by: 4

Related to: 10