Work

Ultrafast competition between CO release and spin crossover upon photoexcitation of a cyclopropenone-bipyridyl Fe II complex

Year: 2025

Type: article

Abstract: ion rather than CO release. This ultrafast response stands out as highly remarkable as it virtually outcompetes the photo-decarbonylation, which in the free ligand occurs in only ∼130 fs.

Source: Physical Chemistry Chemical Physics

DOI: 10.1039/d5cp00019j

Authors: Sebastian Megow, Annika Prax, Tjorge Neumann, Marc Lehr, Anna J. McConnell, Friedrich Temps

Institutions: Christian-Albrechts-Universität zu Kiel, University of Siegen

Language: English

Topic: Magnetism in coordination complexes

Subfield: Electronic, Optical and Magnetic Materials

Field: Materials Science

Domain: Physical Sciences

Open Access status: hybrid

Funder: Deutsche Forschungsgemeinschaft

Award: Photoresponsive metallorganische Käfigverbindungen

OpenAlex ID: W4409267879

FWCI: 0.163

Cites: 38

Cited by: 1

Related to: 10