Work

Optimizing Plasticizer Selection: Insights Into Thermoplastic Polyurethane Performance and Sustainability

Year: 2025

Type: article

Abstract: ABSTRACT Thermoplastic polyurethanes (TPUs) serve as versatile materials bridging rubbers and plastics, increasingly replacing conventional polymeric materials and rubbers in lightweight, cost‐effective, and high‐performance applications. Plasticizers are very useful for tailoring TPU properties to meet application‐specific requirements. This study investigates the plasticization of a polyether‐based TPU using plasticizers with different chemical structures, including benzoate‐ and phosphate‐based types, alongside a bio‐based alternative to move toward greener and more sustainable scenarios. Thermal and mechanical assessments revealed that low molecular weight benzoate plasticizers provided optimal performance with low volatility, offering a viable substitute for the industry‐standard plasticizer. Conversely, high molecular weight benzoates and flame‐retardant phosphate‐based plasticizers exhibited reduced efficacy. The bio‐based plasticizer demonstrated promising potential at concentrations below 30%, although saturation effects limited its performance at higher dosages. These findings highlight the critical role of plasticizer selection and optimization in achieving targeted TPU properties, with implications for sustainable material development in industrial applications.

Source: Journal of Applied Polymer Science

DOI: 10.1002/app.57108

Authors: Ginevra Vongher, Gian Pietro Vianelli, Camillo Cardelli, Andrea Pucci

Institutions: National Research Council, University of Pisa

Language: English

Topic: Polymer Science and PVC

Subfield: Polymers and Plastics

Field: Materials Science

Domain: Physical Sciences

SDG: Responsible consumption and production

Open Access status: bronze

Funder: Università di Pisa