Work

Azadiene‐Linked Carbon‐Organic Frameworks for Enhanced Photocatalytic Efficiency in Organic Synthesis

Year: 2025

Type: article

Abstract: 2D covalent organic frameworks (2D-COFs) have garnered huge attention as a promising platform for solar to chemical energy conversion. In this work, two novel azadiene-linked COFs (COF-JLU236 and COF-JLU237) were designed and successfully synthesized under solvothermal conditions for the first time. And new materials have high crystallinity, large surface area, good durability, and broad absorption range, as well as excellent photoelectric properties. Importantly, they can effectively induce selective oxidation of sulfides and phenylboronic acids under visible light, and show wide substrate adaptability and superior reusability.

Source: Chemistry - A European Journal

DOI: 10.1002/chem.202500934

Authors: Yuxin Hou, Yucheng Jin, Shanshan Zhu, Xiao Xiao, Huijuan Yue, Xiaoming Liu

Institutions: Jilin University, Ulsan National Institute of Science and Technology, Jilin Medical University, State Key Laboratory of Inorganic Synthesis and Preparative Chemistry

Language: English

Topic: Covalent Organic Framework Applications

Subfield: Materials Chemistry

Field: Materials Science

Domain: Physical Sciences

SDG: Affordable and clean energy

Open Access status: bronze

Funders: Natural Science Foundation of Jilin Province, National Natural Science Foundation of China, People's Government of Jilin Province, State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, Jilin University