Work

Photoredox Catalytic Two‐Component Radical β‐Fluoro‐Fluorosulfonamidation Reaction of Styrenes

Year: 2025

Type: article

Abstract: In this study, a visible‐light‐mediated two‐component β‐fluoro‐fluorosulfonamidation reaction of styrenes is demonstrated. The bench‐stable reagent, N‐fluorosulfamoyl‐pyridinium tetrafluoroborate can be used as a photoredox‐active nitrogen‐centered radical precursor and also as the fluoride source. This transformation can convert a series of styrenes to functional group‐enriched products, including substrates with electron‐donating or withdrawing groups, as well as di‐ and tri‐substituents on the CC double bond.

Source: European Journal of Organic Chemistry

DOI: 10.1002/ejoc.202500172

Authors: Yao Huang, Junqi Huang, Peng Wang, Saihu Liao

Institutions: Xiamen University, Fuzhou University, Huaibei Normal University

Language: English

Topic: Radical Photochemical Reactions

Subfield: Organic Chemistry

Field: Chemistry

Domain: Physical Sciences

Open Access status: bronze

Funders: National Natural Science Foundation of China, Xiamen University

Awards: G2453929211, G6968967569