Constructing a 2-electrons Dirac equation in Minkowski space
Year: 2025
Type: conference-paper
Abstract: Quantum mechanics describes multi-electronic systems by using probabilistic theories. All of these theories provide a probabilistic conception of quantum mechanics, with an astonishing accuracy (for instance the Helium atom ground state is computed with more than 20 digits of accuracy) but unfortunately seems to be a bit “disconnected” with macro-scale physics. Indeed, the real observable world is for us a 3D+time Minkowski space but quantum mechanics is expressed in multi-dimensional Hilbert space: which is not intuitively physical but seems to be purely mathematical. In this article we try to construct a relativistic equation that gives an approximately correct description of atomic physics in the spacetime (i.e the “real space”) for 2 electrons systems: i.e a 2-electrons Dirac equation. The starting point is to use the wave mechanics concept of De Broglie and Schrödinger: considering the electron as a matter-wave. For this we start from the Hartree equation, which gives already a spacetime description of each electron wave function. Then, we switch to Hartree-Fock representation, which gives birth to the exchange potential, that can be also expressed in spacetime. By extending the concept of exchange potential to the relativistic 4-exchange: we obtain a relativistic 2-electrons spacetime Dirac-Hartree-Fock (STDHF) equation (i.e in Minkowski space). That equation takes into account relativistic effects but not correlation effects, which is the difficulty of this study. Then we will show the equivalence of the 2-electrons STDHF equation with the Hartree-Fock equation in non-relativistic, stationary and scalar regime. Electron correlation issues will be discussed as well.
Author: Ophelliam Loiselet
Language: English
Topic: Atomic and Molecular Physics
Subfield: Atomic and Molecular Physics, and Optics
Field: Physics and Astronomy
Domain: Physical Sciences
Open Access status: diamond
OpenAlex ID: W4409299447