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Cover Feature: Technetium and Rhenium Auto‐reduction, Polymerization and Lability towards Group VII Polyoxometalate Chemistry (Chem. Eur. J. 21/2025)

Year: 2025

Type: article

Abstract: The hand you are dealt: Reduced TcV/ReVI octahedra and fully oxidized TcVII/ReVII tetrahedra self-assemble, mix and match, and exchange to produce the first group VII technetium/rhenium mixed metal polyoxometalate and the first rigorous characterization of a rhenium autoreduction product. Based on both the lability of the polynuclear clusters and trends in reduction, the expansion of nascent group VII polyoxometalates is promising. More information can be found in the Research Article by M. Nyman and co-workers (DOI: 10.1002/chem.202404144).

Source: Chemistry - A European Journal

DOI: 10.1002/chem.202582104

Authors: Jenna Bustos, Mohammad Shohel, Ana Guilherme Buzanich, Lev Zakharov, Jordi Buils, Mireia Segado‐Centellas, Carles Bo, May Nyman

Institutions: Oregon State University, Federal Institute For Materials Research and Testing, Institut Català d'Investigació Química, Barcelona Institute of Science and Technology, Universitat Rovira i Virgili

Language: English

Topic: Polyoxometalates: Synthesis and Applications

Subfield: Materials Chemistry

Field: Materials Science

Domain: Physical Sciences

Open Access status: bronze

OpenAlex ID: W4409305120

FWCI:

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