Year: 2025
Type: article
Abstract: The synthesis and characterization of a series of imidazolium diorganophosphate‐based surface‐active ionic liquids (SAILs) of the general formula [OMIm][(RO)2PO2] (OMIm = 1‐octyl‐3‐methylimidazolium; R = H, Me, Et, Ph, p‐MeOPh) is reported. The reaction of [OMIm][(RO)2PO2] SAILs with hydrogen peroxide is investigated via 31P‐Nuclear Magnetic Resonance (NMR) spectroscopy, showing the presence of a phosphorous‐peroxo product, which is corroborated by Density Functional Theory (DFT) calculations. The sizes of the SAIL micelles in aqueous hydrogen peroxide are investigated by dynamic light scattering (DLS) before and after addition of cis‐cyclooctene (COE) to study the solubilization of the organic substrate in the aqueous phase. In a model case study, the SAILs are applied as micellar catalysts for the epoxidation of COE under mild conditions.
Institutions: Technical University of Munich, University of Bayreuth
Language: English
Subfield: Catalysis
Field: Chemical Engineering
Domain: Physical Sciences
Open Access status: hybrid
Estimated APC paid: $4,050
Funder: Deutsche Forschungsgemeinschaft
OpenAlex ID: W4409313069