Work

Electrochemical hydrogenative coupling of nitrobenzene into azobenzene over a mesoporous palladium–sulfur cathode

Year: 2025

Type: article

Abstract: O, binary PdS MNSs exhibited a remarkable NB conversion of 95.4%, impressive AZO selectivity of 93.4%, and good cycling stability in selective NB hydrogenation reaction (NBHR) electrocatalysis. Detailed mechanism studies revealed that the confined mesoporous microenvironment of PdS MNSs facilitated the hydrogenative coupling of key intermediates (nitrosobenzene and phenylhydroxylamine) into AZO and/or azoxybenzene (AOB), while their electron-deficient S sites stabilized the Pd-spillovered active H* and inhibited the over-hydrogenation of AZO/AOB into AN. By coupling with the anodic methanol oxidation reaction (MOR), the (-)NBHR‖MOR(+) two-electrode system exhibits much better NB-to-AZO performance in a sustainable and energy-efficient manner. This work thus paves the way for designing functional mesoporous metal alloy electrocatalysts applied in the sustainable electrosynthesis of industrial value-added chemicals.

Source: Chemical Science

DOI: 10.1039/d4sc08608b

Authors: Jie Xiao, Yanzhi Wang, Bo Xiao, Ben Liu

Institution: Sichuan University

Language: English

Topic: Electrocatalysts for Energy Conversion

Subfield: Renewable Energy, Sustainability and the Environment

Field: Energy

Domain: Physical Sciences

SDG: Affordable and clean energy

Open Access status: diamond

Funders: National Key Research and Development Program of China, Fundamental Research Funds for the Central Universities