Work

Magnetically Modified Bentonite for Optimized Erythromycin Removal via RSM and DFT Analysis

Year: 2025

Type: article

Abstract: Erythromycin (ERY), an antibiotic widely used in human and veterinary medicine, persists in the environment due to its low degradability, accumulating in wastewater and soil. This study presents a novel adsorbent synthesized by magnetically modifying calcined natural bentonite with Fe3O4 nanoparticles to enhance ERY removal. The modification increased the surface area, with the highest adsorption observed at pH 11. Adsorption studies revealed that the Dubinin–Radushkevich isotherm model and pseudo-first-order kinetic model best described the adsorption behavior. Response surface methodology (RSM) was employed to optimize key parameters, including adsorbent dosage, temperature, and contact time. The quadratic model indicated optimal conditions of 41.9 mg adsorbent, 29.1 °C, and 9.6 h of contact time, yielding a maximum ERY removal efficiency of 96.2%. Density functional theory (DFT) analysis provided a molecular-level understanding of the adsorption mechanism, identifying strong interactions between ERY, Fe3O4, and bentonite. The theoretical binding energy aligns with experimental results, confirming the role of magnetic modification in promoting ERY adsorption. This study demonstrates a promising approach for mitigating ERY contamination in aqueous environments.

Source: Molecules

DOI: 10.3390/molecules30081792

Authors: Ying-Chieh Hung, Yu-Qi Wu, Ru-Hau Ye, Hsiu-Min Hung, Gui-Bing Hong

Institution: National Taipei University of Technology

Language: English

Topic: Adsorption and biosorption for pollutant removal

Subfield: Water Science and Technology

Field: Environmental Science

Domain: Physical Sciences

SDGs: Clean water and sanitation, Responsible consumption and production

Open Access status: gold

Estimated APC paid: $3,258