Year: 2025
Type: article
Abstract: Structural transformation of high‐nuclearity nanoclusters is of significant interest because of its relevance to the formation mechanisms and stability of metal clusters. Herein, we report three large homoleptic alkynyl‐protected silver nanoclusters, [Ag 98 (2‐CH 3 C 6 H 4 C≡C) 52 ](BF 4 ) 2 , [Ag 86 (2‐CH 3 C 6 H 4 C≡C) 50 ](BF 4 ) 4 , and [Ag 74 (2‐CH 3 C 6 H 4 C≡C) 44 ](BF 4 ) 2 , synthesized from the same precursor 2‐CH 3 C 6 H 4 C≡CAg via fine‐tuning the reduction rate. X‐ray crystallography demonstrates that Ino decahedral Ag 13 units serve as building blocks in all three nanoclusters. Remarkably, Ag 98 undergoes an intercluster transformation in methanol. It initially converts into Ag 74 , then Ag 74 reacts with Ag 98 to form Ag 86 , which eventually is transformed into the thermodynamically stable Ag 74 . Time‐dependent electrospray ionization mass spectrometry (ESI‐MS) confirms such a multi‐step reaction process during the transformation, identifying Ag 86 as the key intermediate. Our findings not only provide new insights into the structural transformation pathways of nanoclusters but also enhance the understanding of transformation mechanisms, contributing to the rational synthesis of high‐nuclearity nanoclusters.
Authors: Lu‐Ming Zheng, Zhen‐Chao Long, Feng Hu, Jiangtao Chan, Wan‐Qi Shi, Ben Zhang, Zhaohui Wang, Quan‐Ming Wang
Institution: Tsinghua University
Language: English
Subfield: Materials Chemistry
Field: Materials Science
Domain: Physical Sciences
Open Access status: bronze
OpenAlex ID: W4409527996