Work

Alcohol electrooxidation on three-component NiO/La2O3/MWCNTs catalyst for DAFC application

Year: 2025

Type: article

Abstract: Alcohol electrooxidation is a crucial reaction in direct alcohol fuel cells (DAFCs), efficiently converting alcohols like methanol and ethanol into electricity with minimal environmental impact, offering a sustainable alternative to fossil fuels. This process is vital for renewable energy technologies, promoting clean energy solutions. Research in this field considers electrocatalyst development, improving reaction kinetics, and reducing fuel cell costs. The wide application of catalyst-based metal oxides led us to synthesize a three-component catalyst, including nickel oxide (NiO)/lanthanum oxide (La 2 O 3 ) catalyst and its hybrid with carbon nanotubes (MWCNT), with the hydrothermal method. The capability of catalysts was investigated in alcohol oxidation reactions (AOR). The successful synthesis of NiO/La 2 O 3 and NiO/La 2 O 3 /MWCNTs catalysts was confirmed. The effect of adding carbon nanotubes to the NiO/La 2 O 3 double metal oxide structure on the methanol and ethanol oxidation reaction (MOR and EOR) was investigated. In MOR and EOR by NiO/La 2 O 3 /MWCNTs catalyst, the maximum current densities of 110.71 and 43.56 mA/cm 2 were obtained at potentials of 0.66 and 0.62 V, respectively, representing relatively good efficiency as a direct alcohol fuel cell (DAFC) catalyst. Also, the comparison of the Tofel slope of NiO/ La 2 O 3 and NiO/La 2 O 3 /MWCNTs catalysts in MOR and EOR processes shows the faster kinetics of the catalyst containing carbon nanotubes in these processes. So, good performance and high stability of catalysts can be promising for further operational investigations. • NiO/La 2 O 3 and NiO/La 2 O 3 /MWCNTs were synthesized as catalysts for alcohol fuel cell anode. • NiO/La 2 O 3 and NiO/La 2 O 3 /MWCNTs show a good performance and stability in MOR and EOR. • The presence of MWCNTs in the structure of the catalyst improved the alcohol electrooxidation.

Source: Electrochemistry Communications

DOI: 10.1016/j.elecom.2025.107936

Authors: Ali Ahmadi, Hadi Ebrahimifar, Mohammad Bagher Askari

Institution: Graduate University of Advanced Technology

Language: English

Topic: Electrocatalysts for Energy Conversion

Subfield: Renewable Energy, Sustainability and the Environment

Field: Energy

Domain: Physical Sciences

SDG: Affordable and clean energy

Open Access status: gold

Estimated APC paid: $2,630