Enhancing energy storage performance in tungsten bronze ceramics utilizing site engineering
Year: 2025
Type: article
Abstract: Advanced electronic systems and innovative pulsed power applications are driving the rapid development of high-energy-storage density and high-efficiency capacitors. In the present study, we have prepared SrBa3.5Sm0.5R0.5Nb9.5O30 (R = Mn, Ti, Sn, Hf) (henceforth referred to as SBSRN) ceramics by solid-phase synthesis, using a site engineering strategy that utilizes tetravalent ions for the substitution of Nb5+ at the B-site of tetragonal phase tungsten bronzes. SBSRN ceramics benefit from site engineering strategies to enhance overall energy storage performance. As a result, they achieve a substantial energy storage density of 4.31 J·cm-3 and an impressive efficiency of 91.3% when subjected to an electric field of 340 kV·cm-1, and show excellent stability in ferroelectric performances with variable temperature and frequency. In addition, these ceramics have a large discharge energy density of 2.68 J·cm-3 and a fast discharge time of 62 ns in charge/discharge tests, along with a current density of 619.96 Acm-2 and a power density of 65.1 MWcm-3. In summary, this research offers a promising method for developing energy storage materials that hold potential for innovative applications in pulsed power components.
Source: Microstructures
Institution: Guilin University of Technology
Language: English
Subfield: Materials Chemistry
Field: Materials Science
Domain: Physical Sciences
Open Access status: hybrid
Award: G999431367
OpenAlex ID: W4409563559