Work

Synergistic Corrosion Inhibition and UV Protection via TTA-Loaded LDH Nanocontainers in Epoxy Coatings

Year: 2025

Type: article

Abstract: To address the issue of metal corrosion in marine environments, we developed a nanofiller with corrosion resistance and UV absorption capabilities. This nanofiller is prepared using a coprecipitation hydrothermal method and consists of TTA intercalated into an LDH structure with an outer layer containing CeO2, forming a layered double hydroxide (LDH) sandwich structure nanocontainer. TTA can be successfully released in corrosive environments, and the filler exhibits excellent corrosion inhibition and interlayer ion exchange properties. Polarization curve analysis shows that the corrosion inhibition efficiency of MgAl-TTA LDH@CeO2 reaches 89.87%. After immersion in a corrosion solution for 60 days, the EP/MgAl-TTA LDH@CeO2 coating maintains a high impedance of 3.88 × 108 Ω·cm2 in the low-frequency region, which is 166 times that of the pure EP coating. Even after 240 h of UV aging, the impedance of the EP/MgAl-TTA LDH@CeO2 coating remains high at 3.10 × 108 Ω·cm2 (20,000 times higher than the pure EP coating). This significantly enhances the coating’s anti-aging and corrosion resistance, providing a feasible method for creating new long-lasting corrosion-resistant coatings in challenging environments.

Source: Coatings

DOI: 10.3390/coatings15050505