Work

Catalytic effect of commercial carbon-coated nickel nanoparticles on the hydrogen storage performance of magnesium hydride

Year: 2025

Type: article

Abstract: Magnesium is an excellent option for hydrogen storage due to its substantial capacity, estimated at approximately 7.6 wt %. However, the desorption temperature usually exceeds 350 °C because of slow kinetics and significant thermodynamic stability. Nickel has been used as a catalyst to enhance the kinetics of MgH 2 hydrogen desorption and absorption, as well as to reduce the dehydrogenation temperature. Commercial carbon-coated nickel nanoparticles were employed to catalyze hydrogen desorption and absorption in MgH 2 . These nanoparticles were incorporated into the MgH 2 through two methods: before and after the ball milling process. Using carbon-coated nickel nanoparticles decreases the onset temperature of dehydrogenation from 321 °C in as-milled MgH 2 to below 255 °C for both sample types containing carbon-coated nickel nanoparticles. The activation energy falls from 152 kJ/mol in as-milled MgH 2 to at least 107 kJ/mol, with a minimum value of 81 kJ/mol. During dehydrogenation at 300 °C, the best samples evaluated take 10 min to reach 6.38 wt % and 40 min to achieve 5 wt % at 275 °C. Furthermore, MgH 2 with commercial carbon-coated nickel nanoparticles absorbs 4.5 wt % of hydrogen in 60 min at 150 °C and has a retention capacity in hydrogen desorption of 92 % after 10 cycles. Our results suggest carbon-coated nickel nanoparticles can be added to MgH 2 without ball milling to catalyze hydrogen desorption and absorption. This type of catalysis may be appealing for nanosized magnesium-based materials, where ball milling can agglomerate particles or alter a specific morphology. • Commercial carbon-coated nickel nanoparticles loaded into MgH 2 . • MgH 2 – 5 wt % C@Ni-MIX absorbs 4.5 wt % of H 2 in 60 min at 150 °C. • MgH 2 – 0.5 wt % C@Ni-BM take 10 min to desorbs 6.38 wt % at 300 °C. • The desorption Ea of MgH 2 – 5 wt % C@Ni-MIX is decreased until 81 kJ/mol.

Source: International Journal of Hydrogen Energy

DOI: 10.1016/j.ijhydene.2025.04.226