Work

In-situ high-throughput nanoelectrochemistry for battery characterization

Year: 2025
Type: review
Abstract: A comprehensive understanding of dynamic structure–activity relationships in materials under operating conditions is essential for improving the efficiency, performance, and lifespan of rechargeable battery systems. Traditional characterization techniques struggle to capture real-time processes within the battery “black box.” The emergence of nanoelectrochemistry provides diverse in-situ and high-throughput toolkits for probing material dynamics at the electrode–electrolyte nanointerface. This review highlights two representative techniques, collision electrochemistry and scanning electrochemical cell microscopy, and demonstrates their ability to monitor transient mass transport and charge transfer kinetics in battery materials and interfaces at nanodomains with sub-millisecond resolution. Additionally, it explores the potential of high-resolution optical imaging to achieve nanoscale visualization of structural spatiodynamics at the single particle–electrolyte interface during charge/discharge over multiple time scales, ranging from milliseconds to hours. Finally, future advancements are envisioned to enable accelerated mechanistic insights, rational material design, and automated discovery of next-generation battery materials.
Language: English
Open Access status: hybrid
Estimated APC paid: $3,630
OpenAlex ID: W4410061038
FWCI: 0.186
Cites: 79
Cited by: 4
Related to: 10