Work

Exploitation of seawater brines for the production of Nesquehonite solids and CO2 utilization

Year: 2025

Type: article

Abstract: The simultaneous utilization of waste CO 2 streams and bivalent rich saline solutions is a crucial opportunity to face climate change challenges. Several authors have investigated desalination seawater brines as promising sources of bivalent solutions for CO 2 utilization technologies. However, the Mg 2 + and Ca 2+ content in brines affects the purity of the synthesized compounds. In this context, the present work thoroughly assesses, for the first time, the direct and indirect mineral carbonation processes of real highly concentrated Mg 2+ -rich saline solutions (bitterns), the latter being the by-products of the evaporation process of seawater or desalination brines in saltworks or evaporative ponds. For comparison, the indirect carbonation process of real desalination brines was also explored. The bittern had Mg 2+ and Ca 2+ concentrations of ∼2.00 mol/L and ∼0.004 mol/L, while ∼0.13 mol/L and ∼0.025 mol/L were those in the desalination brine, respectively. Carbonation tests were conducted at room temperature and atmospheric pressure in a (semi-)batch reactor. The high concentration of Mg 2+ and the almost absence of Ca 2+ in the bittern allowed (i) the production of highly pure Nesquehonite solids (purity ∼99 %) and (ii) almost doubling the CO 2 yield (from 23 % to 37 %) through the direct carbonation approach against the indirect one.

Source: Journal of CO2 Utilization

DOI: 10.1016/j.jcou.2025.103101

Authors: Giuseppe Battaglia, Michela Cardella, Alessandro Tamburini, Andrea Cipollina, Giorgio Micale

Institution: University of Palermo

Language: English

Topic: CO2 Sequestration and Geologic Interactions

Subfield: Environmental Engineering

Field: Environmental Science

Domain: Physical Sciences

SDGs: Climate action, Responsible consumption and production

Open Access status: gold

Estimated APC paid: $3,360