Work

Non‐Aqueous Electrochemical CO 2 Reduction to Multivariate C 2 ‐Products Over Single Atom Catalyst at Current Density up to 100 mA cm −2 (Small 18/2025)

Year: 2025

Type: article

Abstract: CO2 Reduction In article number 2408010, Meenesh R. Singh and co-workers explore a conductive, stable Zr-based porphyrin metal–organic framework (MOF), PCN-222, metalated with single-atom Cu for CO2 reduction. PCN-222(Cu) achieves ∼100 mA cm−2 current density and 40% faradaic efficiency for acetate, outperforming previous MOF systems. X-ray and spectroscopic analyses provide key insights into its catalytic mechanism, advancing MOF-based single-atom catalysis.

Source: Small

DOI: 10.1002/smll.202570143

Authors: Rajan R. Bhawnani, Rohan Sartape, Vamsi V Gande, Michael L. Barsoum, Elias M. Kallon, Roberto dos Reis, Vinayak P. Dravid, Meenesh R. Singh

Institutions: University of Illinois Chicago, Northwestern University, International Institute for Nanotechnology

Language: English

Topic: CO2 Reduction Techniques and Catalysts

Subfield: Renewable Energy, Sustainability and the Environment

Field: Energy

Domain: Physical Sciences

SDGs: Affordable and clean energy, Climate action

Open Access status: bronze

OpenAlex ID: W4410091849

FWCI: 0.142

Cites:

Cited by: 1

Related to: 10