Work

High yield methane production from the hydrogenation of CO₂ using non-thermal plasma/catalysis

Year: 2025

Type: article

Abstract: In this work, a dielectric barrier discharge (DBD) non-thermal plasma/catalytic reactor was used under a range of process conditions, designed to maximise the hydrogenation of CO₂ to methane. A Ni/Al₂O₃ catalyst was used in the plasma/catalysis reactor and the process parameters investigated were the effect of input plasma power, catalyst temperature, catalyst weight hourly space velocity (WHSV), and H₂/CO₂ ratio in relation to the methanation of CO₂. In addition, the effect of the catalyst active metal type (ruthenium, cobalt, and lanthanum) supported on Al₂O₃ under the optimum reaction conditions was investigated. The optimised system, using Ni/Al 2 O 3 , achieved a CO₂ conversion of 82.2 % with an energy efficiency of 22.5 g CO₂ kWh −1 , CH₄ selectivity of 90.2 % and energy efficiency of 7.4 g CH₄ kWh −1 at the plasma input power of 70 W, catalyst temperature of 280 °C, catalyst WHSV of 768 ml/g cat h, and H₂/CO₂ ratio of 4. The performance of the active catalyst metals in relation to CO₂ conversion to methane was Ru > Ni > Co > La.

Source: Fuel Processing Technology

DOI: 10.1016/j.fuproc.2025.108228

Authors: Maryam Khatibi, Paul T. Williams

Institution: University of Leeds

Language: English

Topic: Catalysts for Methane Reforming

Subfield: Catalysis

Field: Chemical Engineering

Domain: Physical Sciences

SDGs: Affordable and clean energy, Climate action

Open Access status: gold

Estimated APC paid: $3,180