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Enhanced paraben removal through synergistic catalytic ozonation and adsorption processes using Fe3O4-GAC magnetic composite

Year: 2025
Type: article
Abstract: The potential long-term deleterious effects of parabens on ecosystems, particularly as endocrine disruptors, have been a source of concern due to their persistent presence in natural waters. This study evaluated the catalytic performance of Fe 3 O 4 -enhanced granular activated carbon (Fe 3 O 4 -GAC) in the catalytic ozonation of methyl-paraben (MP) and ethyl-paraben (EP). Characterization confirmed that Fe 3 O 4 nanoparticle improved GAC’s surface properties, enhancing reaction efficiency. Under optimized conditions (1.5 g/L GAC, pH 3, 20 mg/L parabens, 45 min), the adsorption process achieved removal efficiencies of 70% for MP and 65% for EP. Fe 3 O 4 -GAC outperformed ozonation and catalytic ozonation with GAC, removing 98% of MP and 95% of EP at pH 9, 1 g/L catalyst, and 5 min of reaction time. Adsorption kinetics followed the pseudo -first-order kinetic model with higher determination coefficients (R 2 : 0.9369 for MP, 0.9164 for EP) than the pseudo -second-order model, while the Langmuir isotherm best described the process (R 2 : 0.9782 for MP, 0.9933 for EP). Degradation in catalytic ozonation using Fe 3 O 4 -GAC also followed the pseudo -first-order kinetic model, achieving rate constants of 0.4437 min⁻ 1 for MP and 0.3076 min⁻ 1 for EP. Moreover, the catalyst demonstrated excellent reusability, maintaining high performance after five successive cycles. These findings underline the potential of Fe 3 O 4 -GAC as a sustainable and efficient catalyst for removing parabens from water, addressing an urgent environmental challenge.
DOI: 10.1007/s13201-025-02475-5
Language: English
Open Access status: gold
Estimated APC paid: $2,490
OpenAlex ID: W4410144619
FWCI: 1.545
Cites: 46
Cited by: 6
Related to: 10