Work

Radioiodide Sorption on Natural and Acid-Treated Zeolite

Year: 2025

Type: article

Abstract: This work is devoted to the study of the effect of acid treatment on the structural and textural properties of natural zeolite and its sorption activity with respect to radioiodide. To carry out the experiments, natural zeolite was treated with nitric acid of various concentrations at 20 and 90 degrees. The following methods were used to study the samples: XRD, SEM, DTA, XRF, FTIR, BET, and CEC analyses. Experiments on the sorption and desorption of radioiodide were carried out. The obtained results indicate that acid treatment results in the gradual leaching of aluminum from the crystal lattice and a significant increase in the specific surface area and microporosity of the zeolite. At the same time, the morphology of clinoptilolite is not significantly changed. Additional studies have shown that acid treatment leads to the hydrophobization of zeolite channels and the formation of an amorphous aluminosilicate phase, which makes a significant contribution to the increase in the specific surface area and microporosity. It was found that, with an increase in the degree of dealumination of the zeolite, there is an increase in the sorption properties with respect to radioiodide. The maximum values of sorption capacity were obtained after treating the zeolite with a 1 M nitric acid solution at 90 °C. With a further increase in the concentration of acid, critical changes in the structure of the zeolite occur, leading to a sharp decrease in the sorption capacity. Iodide sorption is not associated with physical adsorption in the micropores of the zeolite and the newly formed amorphous phase. The main mechanism of the sorption appears to be the interaction with silanol and bridging hydroxyl groups on the surface of the zeolite and the amorphous aluminosilicate phase.

Source: Minerals

DOI: 10.3390/min15050494