Work

Accurate prediction of carbon monoxide in aqueous solutions for geological sequestration applications

Year: 2025

Type: article

Abstract: Accurate prediction of solubilities in aqueous solutions is crucial for the geological sequestration of carbon monoxide (CO). This study utilizes the electrolyte version of the Cubic-Plus-Association (CPA) Equation of State to calculate the saturated properties including saturated vapor pressure, saturated liquid-phase density, and saturated vapor-phase density of pure CO, its solubilities in pure water, and its solubilities in aqueous sodium chloride solutions. The model accuracy is validated against experimental data, showing relative average deviations within 3.0% for saturated liquid-phase density, within 1.0% for both saturated vapor pressure and saturated vapor-phase density, 4.7% for CO solubilities in pure water, and 1.3% for CO solubilities in aqueous sodium chloride solutions. This work not only analyzes the phase behavior of CO in aqueous solutions but also provides an in-depth discussion on the dissolution mechanisms of CO in these solutions. The results demonstrate that the electrolyte version of the CPA Equation of State is a robust model capable of accurately predicting CO solubilities and the complex phase behavior of CO in aqueous solutions across a wide range of temperatures, pressures, and salt concentrations.

Source: Applied Geochemistry

DOI: 10.1016/j.apgeochem.2025.106414

Authors: Li Sun, Jierong Liang

Institutions: Hohai University, Shanghai Ocean University, Helmholtz-Zentrum Dresden-Rossendorf

Language: English

Topic: Phase Equilibria and Thermodynamics

Subfield: Biomedical Engineering

Field: Engineering

Domain: Physical Sciences

SDG: Climate action

Open Access status: hybrid

Estimated APC paid: $3,490