Work

Six-coordinated half-metallocene catalyst for ethylene polymerization and its mechanism study

Year: 2025

Type: article

Abstract: The demand for catalysts capable of enabling olefin polymerization at elevated temperatures to meet industrial requirements continues to grow. Among emerging candidates, novel six-coordinated half-metallocene catalysts, which combine the advantages of both metallocenes and non-metallocenes, show promise due to their polymerization performance and thermal stability. Despite this potential, the polymerization mechanism of six-coordinated half-metallocenes with one chloride ligand has not been clarified yet and theoretical calculation of new catalysts in olefin polymerization is an indispensable means for catalyst design and mechanism research. Herein, we present the synthesis and application of a six-coordinated half-zirconocene catalyst that exhibits outstanding polymerization activity under high-temperature conditions. Besides, we elucidate the polymerization process through a combination of theoretical studies and experimental validations. Furthermore, the chain transfer reaction during the polymerization was analyzed by the characterization of polymer.

Source: Giant

DOI: 10.1016/j.giant.2025.100360