Work

Diastereoselective Umpolung cyclisation of ketones promoted by hypervalent iodine

Year: 2025

Type: article

Abstract: -substituted cyclohexanes. Additional investigations, both experimental and computational, give insight into the mechanistic intricacies of this process, and shed light on an unconventional iodine(iii)-reactivation mechanism.

Source: Chemical Science

DOI: 10.1039/d5sc01085c

Authors: Giulia Iannelli, Philipp Spieß, Ricardo Meyrelles, Daniel Kaiser, Boris Maryasin, Leticia González, Nuno Maulide

Institution: University of Vienna

Language: English

Topic: Oxidative Organic Chemistry Reactions

Subfield: Organic Chemistry

Field: Chemistry

Domain: Physical Sciences

Open Access status: diamond

Funders: Austrian Science Fund, Universität Wien, HORIZON EUROPE European Research Council

Awards: SHUTTLE – Hydride Shuttle Catalysis, G2049608569, G4172719519

OpenAlex ID: W4410327483

FWCI: 0.869

Cites: 35

Cited by: 3

Related to: 10